I cannot say i have machined cast steel but have machined enough cast iron to fill a 1000 barrels of chip. I spit up black crap for a year after that nasty ass job. The smell is distictive and the feel obvious.
When cutting the teeth to accomodate an oring chain, it sure seemed and smelled like cast iron. I may be wrong for i only know half the story.
When googling the difference, it would seem the either would work for this application.
The spark test will surely tell. Dim orange for iron, brighter yellow for steel.
Madass, I hope you are doing what i think your.