Considering that air is compressible and is the element we are trying to purge, I don't think I'd want to apply it intentionally into the system.
Yes, the bleeder screw is the highest point of the caliper, but bubbles can be trapped anywhere up the line also, and even in the MC. It wd be interesting to see a cutaway view of the caliper, showing the paths of the passages; maybe there are internal "high spots" where bubbles can hide, stuck to the walls?
I think that's why a lot of people do the "reverse bleed", injecting fluid into the bleeder valve and pushing the fluid with any bubbles up, so they can escape to atmosphere in the reservoir, which is the direction they try to move anyway.
Almost everyone recommends tying the lever back to the grip after bleeding, and leaving it there overnight, before looking for other problems.
I'm following this with interest, as I will soon be installing Don Pender's sleeve kit for the MC.